Research Summary
Research utilizes advanced spectroscopic and electrochemical approaches to understand the mechanisms and thermodynamics of environmental redox processes with the goal of developing a quantitative understanding of these processes to develop better predictive models and risk assessment tools. Especially interested in mineral formation and transformation reactions that affect environmental pollutant fate and can be used for energy production, storage, and recovery.
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Projects
Recent Publications
Determining desired sorbent properties for proton-coupled electron transfer-controlled CO2 capture using an adaptive sampling-refined classifier
Boualavong, J., Papakonstantinou, K. G. & Gorski, C. A., Jun 15 2023, In: Chemical Engineering Science. 274, 118673.Research output: Contribution to journal ⺠Article ⺠peer-review
System efficiency and power assessment of the all-aqueous copper thermally regenerative ammonia battery
Cross, N. R., Rau, M., Lvov, S. N., Gorski, C. A., Logan, B. E. & Hall, D. M., Jun 1 2023, In: Applied Energy. 339, 120959.Research output: Contribution to journal ⺠Article ⺠peer-review
Disentangling the size-dependent redox reactivity of iron oxides using thermodynamic relationships
Chen, G., Thompson, A. & Gorski, C. A., Oct 4 2022, In: Proceedings of the National Academy of Sciences of the United States of America. 119, 40, e2204673119.Research output: Contribution to journal ⺠Article ⺠peer-review
Power and energy capacity tradeoffs in an all-aqueous copper thermally regenerative ammonia battery
Cross, N. R., Rau, M. J., Lvov, S. N., Gorski, C. A., Logan, B. E. & Hall, D. M., May 30 2022, In: Journal of Power Sources. 531, 231339.Research output: Contribution to journal ⺠Article ⺠peer-review
Spectroelectrochemical Examination of the Ferro-Ferricyanide Redox Reaction: Impacts of Electrode Thickness and Applied Potential
Ganesan, A., Zimudzi, T. J., Pothanamkandathil, V., Gorski, C. A. & Hall, D. M., Oct 2022, In: Journal of the Electrochemical Society. 169, 10, 106501.Research output: Contribution to journal ⺠Article ⺠peer-review
Quantifying the rate of Fe2+-catalyzed recrystallization based on a unifying model framework
Joshi, P., Fantle, M. S., Boualavong, J. & Gorski, C. A., Nov 1 2022, In: Geochimica et Cosmochimica Acta. 336, p. 423-435 13 p.Research output: Contribution to journal ⺠Article ⺠peer-review
Comparing energy demands and longevities of membrane-based capacitive deionization architectures
Pothanamkandathil, V. & Gorski, C. A., May 26 2022, In: Environmental Science: Water Research and Technology. 8, 7, p. 1489-1496 8 p.Research output: Contribution to journal ⺠Article ⺠peer-review
Co-precipitation synthesis control for sodium ion adsorption capacity and cycle life of copper hexacyanoferrate electrodes in battery electrode deionization
Shi, L., Bi, X., Newcomer, E., Hall, D. M., Gorski, C. A., Galal, A. & Logan, B. E., May 1 2022, In: Chemical Engineering Journal. 435, 135001.Research output: Contribution to journal ⺠Article ⺠peer-review
Thermodynamic and Kinetic Analyses of Ion Intercalation/Deintercalation Using Different Temperatures on NiHCF Electrodes for Battery Electrode Deionization
Shi, L., Bi, X., Newcomer, E., Hall, D. M., Gorski, C. A. & Logan, B. E., Jun 21 2022, In: Environmental Science and Technology. 56, 12, p. 8932-8941 10 p.Research output: Contribution to journal ⺠Article ⺠peer-review
Influence of Hydrotropes on the Solubilities and Diffusivities of Redox-Active Organic Compounds for Aqueous Flow Batteries
Cheng, Y., Hall, D. M., Boualavong, J., Hickey, R. J., Lvov, S. N. & Gorski, C. A., Nov 16 2021, In: ACS Omega. 6, 45, p. 30800-30810 11 p.Research output: Contribution to journal ⺠Article ⺠peer-review
Optimizing Electrodeposited Manganese Oxide at Carbon Cloth Electrodes for Harvesting Salinity-Gradient Energy
Fortunato, J., Sassin, M. B., Chervin, C. N., Parker, J. F., Deblock, R. H., Gorski, C. A. & Long, J. W., Feb 2021, In: Journal of the Electrochemical Society. 168, 2, 024505.Research output: Contribution to journal ⺠Article ⺠peer-review
Effects of Fe(III) oxide mineralogy and phosphate on Fe(II) secondary mineral formation during microbial iron reduction
Oâloughlin, E. J., Boyanov, M. I., Gorski, C. A., Scherer, M. M. & Kemner, K. M., Feb 2021, In: Minerals. 11, 2, p. 1-43 43 p., 149.Research output: Contribution to journal ⺠Article ⺠peer-review
Using a vapor-fed anode and saline catholyte to manage ion transport in a proton exchange membrane electrolyzer
Rossi, R., Hall, D., Shi, L., Cross, N. R., Gorski, C. A., Hickner, M. A. & Logan, B. E., Nov 2021, In: Energy and Environmental Science. 14, 11, p. 6041-6049 9 p.Research output: Contribution to journal ⺠Article ⺠peer-review
Metal-Ion Depletion Impacts the Stability and Performance of Battery Electrode Deionization over Multiple Cycles
Shi, L., Newcomer, E., Son, M., Pothanamkandathil, V., Gorski, C. A., Galal, A. & Logan, B. E., Apr 20 2021, In: Environmental Science and Technology. 55, 8, p. 5412-5421 10 p.Research output: Contribution to journal ⺠Article ⺠peer-review
An All-Aqueous Thermally Regenerative Ammonia Battery Chemistry Using Cu(I, II) Redox Reactions
Springer, R., Cross, N. R., Lvov, S. N., Logan, B. E., Gorski, C. A. & Hall, D. M., Jul 2021, In: Journal of the Electrochemical Society. 168, 7, 070523.Research output: Contribution to journal ⺠Article ⺠peer-review