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Recent Publications
The role of surface hydroxyls in the entropy-driven adsorption and spillover of H2 on Au/TiO2 catalysts
Mahdavi-Shakib, A., Whittaker, T. N., Yun, T. Y., Sravan Kumar, K. B., Rich, L. C., Wang, S., Rioux, R. M., Grabow, L. C. & Chandler, B. D., Aug 2023, In: Nature Catalysis. 6, 8, p. 710-719 10 p.Research output: Contribution to journal › Article › peer-review
Surface Hydroxyl Chemistry of Titania- and Alumina-Based Supports: Quantitative Titration and Temperature Dependence of Surface Brønsted Acid-Base Parameters
Yun, T. Y. & Chandler, B. D., Feb 8 2023, In: ACS Applied Materials and Interfaces. 15, 5, p. 6868-6876 9 p.Research output: Contribution to journal › Article › peer-review
Hydrogen Adsorption at the Au/TiO2 Interface: Quantitative Determination and Spectroscopic Signature of the Reactive Interface Hydroxyl Groups at the Active Site
Mahdavi-Shakib, A., Rich, L. C., Whittaker, T. N. & Chandler, B. D., Dec 17 2021, In: ACS Catalysis. 11, 24, p. 15194-15202 9 p.Research output: Contribution to journal › Article › peer-review
Kinetics of H2 Adsorption at the Metal–Support Interface of Au/TiO2 Catalysts Probed by Broad Background IR Absorbance
Mahdavi-Shakib, A., Kumar, K. B. S., Whittaker, T. N., Xie, T., Grabow, L. C., Rioux, R. M. & Chandler, B. D., Mar 29 2021, In: Angewandte Chemie - International Edition. 60, 14, p. 7735-7743 9 p.Research output: Contribution to journal › Article › peer-review
Supported Ni-Au Colloid Precursors for Active, Selective, and Stable Alkyne Partial Hydrogenation Catalysts
Bruno, J. E., Dwarica, N. S., Whittaker, T. N., Hand, E. R., Guzman, C. S., Dasgupta, A., Chen, Z., Rioux, R. M. & Chandler, B. D., Feb 21 2020, In: ACS Catalysis. 10, 4, p. 2565-2580 16 p.Research output: Contribution to journal › Article › peer-review
Combining Benzyl Alcohol Oxidation Saturation Kinetics and Hammett Studies as Mechanistic Tools for Examining Supported Metal Catalysts
Mahdavi-Shakib, A., Sempel, J., Babb, L., Oza, A., Hoffman, M., Whittaker, T. N., Chandler, B. D. & Austin, R. N., Sep 4 2020, In: ACS Catalysis. 10, 17, p. 10207-10215 9 p.Research output: Contribution to journal › Article › peer-review
Water Poisons H2 Activation at the Au-TiO2 Interface by Slowing Proton and Electron Transfer between Au and Titania
Sravan Kumar, K. B., Whittaker, T. N., Peterson, C., Grabow, L. C. & Chandler, B. D., Mar 25 2020, In: Journal of the American Chemical Society. 142, 12, p. 5760-5772 13 p.Research output: Contribution to journal › Article › peer-review
On the Limited Role of Electronic Support Effects in Selective Alkyne Hydrogenation: A Kinetic Study of Au/MO x Catalysts Prepared from Oleylamine-Capped Colloidal Nanoparticles
Bruno, J. E., Sravan Kumar, K. B., Dwarica, N. S., Hüther, A., Chen, Z., Guzman, C. S., Hand, E. R., Moore, W. C., Rioux, R. M., Grabow, L. C. & Chandler, B. D., Mar 20 2019, In: ChemCatChem. 11, 6, p. 1650-1664 15 p.Research output: Contribution to journal › Article › peer-review
Evaluating differences in the active-site electronics of supported Au nanoparticle catalysts using Hammett and DFT studies
Kumar, G., Tibbitts, L., Newell, J., Panthi, B., Mukhopadhyay, A., Rioux, R. M., Pursell, C. J., Janik, M. & Chandler, B. D., Mar 1 2018, In: Nature Chemistry. 10, 3, p. 268-274 7 p.Research output: Contribution to journal › Article › peer-review
CO Oxidation Kinetics over Au/TiO2 and Au/Al2O3 Catalysts: Evidence for a Common Water-Assisted Mechanism
Saavedra, J., Pursell, C. J. & Chandler, B. D., Mar 14 2018, In: Journal of the American Chemical Society. 140, 10, p. 3712-3723 12 p.Research output: Contribution to journal › Article › peer-review
H 2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H 2 Activation at the Metal-Support Interface
Whittaker, T., Kumar, K. B. S., Peterson, C., Pollock, M. N., Grabow, L. C. & Chandler, B. D., Dec 5 2018, In: Journal of the American Chemical Society. 140, 48, p. 16469-16487 19 p.Research output: Contribution to journal › Article › peer-review
An extra layer of complexity
Chandler, B. D., Jan 24 2017, In: Nature Chemistry. 9, 2, p. 108-109 2 p.Research output: Contribution to journal › Short survey › peer-review
Two-Color Metal-Enhanced Fluorescence Using Gold Slotted Nanogratings
Hure, R., Simoneau, S., Chandler, B. D. & Steele, J. M., Oct 1 2017, In: Plasmonics. 12, 5, p. 1621-1626 6 p.Research output: Contribution to journal › Article › peer-review
Water Influences the Activity and Selectivity of Ceria-Supported Gold Catalysts for Oxidative Dehydrogenation and Esterification of Ethanol
Mullen, G. M., Evans, E. J., Sabzevari, I., Long, B. E., Alhazmi, K., Chandler, B. D. & Mullins, C. B., Feb 3 2017, In: ACS Catalysis. 7, 2, p. 1216-1226 11 p.Research output: Contribution to journal › Article › peer-review
Co adsorption on Au/Tio2 Catalysts: Observations, quantification, and explanation of a broad-band infrared signal
Powell, C. D., Daigh, A. W., Pollock, M. N., Chandler, B. D. & Pursell, C. J., 2017, In: Journal of Physical Chemistry C. 121, 39Research output: Contribution to journal › Article › peer-review